Major appearances
Machop debuted in The Punchy Pokémon as the first opponent for Ash and his Primeape in the P1 Grand Prix.
A Machop appeared in Pop Goes The Sneasel as one of the Pokémon protecting the flame of Ho-Oh at a shrine.
A Machop appeared in Brave the Wave, under the ownership of Brawly. It was used during his Gym battle against Ash, where it defeated Taillow before being defeated by Treecko. Machop reappeared in Just One of the Geysers, where it was used during Ash's rematch. During that battle, Machop was defeated by Ash's newly-caught Corphish. It reappeared in a flashback in Which Wurmple's Which?.
A Machop appeared in Sitting Psyduck, under the ownership of Emily. It, Machoke, and Machamp chased after her runaway Psyduck.
Minor appearances
A Machop appeared in Riddle Me This as one of the Fighting-type Pokémon in an exercise Gym that were targeted by Team Rocket.
A Machop appeared in The Power of One.
Two wild Machop appeared in Pikachu's Rescue Adventure. One helped the Trainers' Pokémon and Elekid save the Exeggcute nests and Togepi during a storm.
A Machop appeared in Pokémon Double Trouble.
A Trainer's Machop appeared in Two Hits and a Miss, where it was one of the many Pokémon at a Fighting-type dojo.
A Machop appeared in a fantasy in A Better Pill to Swallow.
A Machop appeared in Machoke, Machoke Man! as one of the Pokémon seen at the Cianwood Gym.
A Machop appeared in A Double Dilemma as a resident of North Petalburg.
A Coordinator's Machop appeared in Weekend Warrior, where it participated in the Silver Town Pokémon Contest.
A Machop appeared in Spontaneous Combusken!, where it was seen at the Chrysanthemum Island beach.
A Machop appeared in To Thine Own Pokémon Be True! and BWS02.
A Trainer's Machop appeared in The Journalist from Another Region!, where it was entered into the Pokémon Sumo Tournament on Harvest Island.
A Machop appeared in a flashback or a fantasy in The Forest Champion!.
A Machop appeared in a flashback in When Light and Dark Collide!.
A Machop appeared in A Festival of Decisions!, where it helped arrest the rogue ninjas that attacked the Ninja Village.
Three Trainers' Machop appeared in Alola to New Adventure!.
Three Trainers' Machop appeared in A Shocking Grocery Run!.
Two Trainers' Machop appeared in Racing to a Big Event!, where they participated in the Pokémon Pancake Race.
Two Machop appeared in Rocking Clawmark Hill! as some of the Pokémon training up on Clawmark Hill.
A Trainer's Machop appeared in They Might Not Be Giants!.
Three Trainers' Machop appeared in One Journey Ends, Another Begins....
A Trainer's Machop appeared in Getting the Band Back Together!.
Three Trainers' Machop appeared in A Glaring Rivalry!.
A Trainer's Machop appeared in I Choose You!, where it had a battle with Pikachu.
Two Trainers' Machop appeared in Balloons, Brionne, and Belligerence!.
A Trainer's Machop appeared in Alola, Kanto!.
A Trainer's Machop appeared in Smashing with Sketch!, where it participated in the Pokémon Ping-Pong tournament.
A Trainer's Machop appeared in Sours for the Sweet!.
A Trainer's Machop appeared in Twirling with a Bang!.
Two Trainers' Machop appeared in A Young Royal Flame Ignites!.
Six Trainers' Machop appeared in The Power of Us.
A Trainer's Machop appeared in The Shape of Love to Come!.
A Trainer's Machop appeared in We Know Where You're Going, Eevee!.
A Trainer's Machop appeared in Heart of Fire! Heart of Stone!.
A Trainer's Machop appeared in The Dealer of Destruction!.
A Trainer's Machop appeared in League Offenders and Defenders!.
A Trainer's Machop appeared in SM134.
A Trainer's Machop appeared in SM140.
A Trainer's Machop appeared in SM141.
Two Trainers' Machop appeared in SM146.
Pokédex entries
Episode
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Pokémon
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Source
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Entry
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AG020
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Machop
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May's Pokédex
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Machop, the Superpower Pokémon. Machop have muscles that never tire, no matter how much they exercise. Machop have enough strength to throw 100 average-sized adults.
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In the Pocket Monsters HeartGold & SoulSilver Go! Go! Pokéathlon manga
A Machop appeared in Pocket Monsters HeartGold & SoulSilver Go! Go! Pokéathlon.
In the Pokémon Adventures manga
Machop debuted in a flashback Long Live the Nidoqueen!?, under the ownership of Harry.
Bruno owns several Machop, which first appeared in Karate Machop!. They were sent to attack Kanto alongside several other Elite Four Pokémon.
A Machop appeared in Querulous Qwilfish, where it was aiding the construction of the Battle Tower.
A Machop was seen in Mashing Makuhita as one of Brawly's Pokémon, which he sent out against Sapphire's Combusken, but it ended up overwhelmed by its speed. Much later, in Volume 20, Brawly was shown to own a Machoke, which appeared to have evolved from the same Machop.
A Machop appeared in The Final Battle IV, where it was one of the Pokémon that helped Emerald with his disabilities.
A Machop appeared in Perturbed by Pachirisu.
A Machop appears with its Trainer at the Mini-game Corner in the X & Y arc.
In the Pokémon Gold & Silver: The Golden Boys manga
A Machop appeared in Let's Fight! The Mini Pokémon Tournament.
A Machop appeared in a flashback in Let's Fight For The Future!!.
In the Pokémon Gotta Catch 'Em All manga
A Machop appeared in Pokémon Cooking Contest!, under the ownership of Yuki.
In the Pokémon + Nobunaga's Ambition ~ Ranse's Color Picture Scroll ~ manga
A Machop appeared in The Yellow Scroll: Hanbei vs Kanbei.
A Machop appeared in The Black Scroll: Nobunaga's Ambition.
In the Pokémon Pocket Monsters manga
Giovanni's Machop briefly appeared in Get The Last Badge!! along with its evolved form.