In the main series
Major appearances
Both Misty and Daisy have a Luvdisc, nicknamed Caserin and Luverin. They acquired the two Rendezvous Pokémon prior to Luvdisc is a Many Splendored Thing!. They found themselves the target of Butch and Cassidy under instructions from Dr. Namba.
Other
Juan owns a Luvdisc that first appeared in The Great Eight Fate!. It was used in the following episode, during the Gym battle against Ash. Luvdisc first battled against Grovyle and won, but later lost against Corphish.
Minor appearances
Multiple Luvdisc debuted in Clamperl of Wisdom as some of the Pokémon living at Maisie Island.
Multiple wild Luvdisc appeared of Pokémon Ranger and the Temple of the Sea. They briefly reappeared in a montage in The Rise of Darkrai, which chronicled the preceding nine movies.
Multiple Luvdisc appeared in the opening sequences of Giratina and the Sky Warrior and Zoroark: Master of Illusions.
A few Luvdisc appeared in Hold the Phione! as residents of Chocovine Town.
Multiple Luvdisc appeared in Kalos, Where Dreams and Adventures Begin!.
Multiple Luvdisc appeared in Going for the Gold!, where they were among the Pokémon seen in the Ambrette Aquarium.
Multiple Luvdisc appeared in An Undersea Place to Call Home!, where they were among the Pokémon who made the wreck of the S.S. Cussler their home.
Multiple Luvdisc appeared in Diancie and the Cocoon of Destruction.
Multiple Luvdisc appeared in Alola to New Adventure!.
Two Luvdisc appeared in The Guardian's Challenge!, A Shocking Grocery Run!, That's Why the Litten is a Scamp!, Alolan Open House!, A Dream Encounter!, Night of a Thousand Poses!, The Professors' New Adventure!, The Dex Can't Help It!, and SM081, where they were residing in Professor Kukui's lab alongside a Corsola.
Three Luvdisc appeared in Yo, Ho, Ho! Go, Popplio!.
Multiple Luvdisc appeared in The Sun, the Scare, the Secret Lair!.
A Luvdisc appeared in A Shivering Shovel Search!.
Multiple Luvdisc appeared in The Island Whisperer!.
Multiple Luvdisc appeared in Balloons, Brionne, and Belligerence!.
Multiple Luvdisc appeared in Now You See Them, Now You Don't!.
Two Luvdisc appeared in Night of a Thousand Poses!.
Multiple Luvdisc appeared in Let Sleeping Pokémon Lie!.
Multiple Luvdisc appeared in SM071. They were swimming in the ocean before they were scared away by a Sharpedo.
Pokédex entries
Episode
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Pokémon
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Source
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Entry
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AG110
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Luvdisc
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May's Pokédex
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Luvdisc, the Rendezvous Pokémon. Luvdisc group together during breeding season, covering the surface of the ocean in a brilliant pink.
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In Pokémon Generations
Multiple wild Luvdisc appeared in the waters that surrounded the Mossdeep Space Center in The Cavern.
In the Pokémon Adventures manga
Wallace has a Luvdisc nicknamed Elizabeth that debuted in Short Shift for Shiftry. She is usually shown out of her Poké Ball, floating along beside him. Wallace relies on her to solve problems, as she is shown doing such things as putting out a burning scarf and releasing a Lileep and Anorith to test Ruby's worth at Wallace's request. Also, the two seem to share a bond, as he rarely, if ever, has to specify what he wants her to do. Like all of Wallace's Pokémon in the manga, she is incredibly beautiful and was able to defeat all of Ruby's top Contest Pokémon, excluding Feefee, in an unofficial Contest in a matter of minutes.
Wallace's mentor, Juan, also uses a pair of Luvdisc that first appeared in With a Spoink in Your Step II, who observe him as he trained Ruby and Sapphire.
The Battle Factory rented a Luvdisc which was stolen by Guile Hideout in The Final Battle VII.
Multiple Luvdisc appeared in PS541.
In the Pokémon Omega Ruby Crimson Passion and Pokémon Alpha Sapphire Indigo Wisdom manga
Some Luvdisc appeared while Alpha and Omega dove underwater with their Wailmer.