In Ka Boom with a View!, Venusaur was used as the second Pokémon in the battle at the Battle Palace, after Shiftry. Ash used Heracross for the battle. It was able to put up a good fight, but was eventually defeated by Venusaur's powerful Solar Beam. Ash then sent out Swellow, who utilized its speed and agility to its full advantage. It was able to defeat Venusaur after a hard fought battle.
Venusaur was seen being friendly towards the Pokémon as seen in its debut appearance when it went out of its way to make medicine for Pikachu when he was found by Spenser after the current gave Pikachu problems. Venusaur also stopped the Beedrill with Sweet Scent when they were chasing Ash and Sceptile.