These products introduce Pokémon V-UNION to the TCG and, much like Pokémon LEGEND in the HeartGold & SoulSilver Series, require muiltiple cards to be played together. Pokémon V-UNION comprise four separate parts, each of which are included in one of the following sets:
- Greninja V-UNION Special Card Set (Japanese: スペシャルカードセット ゲッコウガV-UNION)
- Mewtwo V-UNION Special Card Set (Japanese: スペシャルカードセット ミュウツーV-UNION)
- Zacian V-UNION Special Card Set (Japanese: スペシャルカードセット ザシアンV-UNION)
Individual Pokémon V-UNION parts have different numbers and the assembly form a numbered master set. Each set also includes a Supporter card depicting Professor Burnet that can aid players in discarding Pokémon V-UNION cards and bring them into play, plus three Skyscraping Perfection booster packs and three Blue Sky Stream booster packs.