These products introduce Pokémon V-UNION to the TCG and, much like Pokémon LEGEND in the HeartGold & SoulSilver Series, require muiltiple cards to be played together. Pokémon V-UNION comprise four separate parts, each of which are included in one of the following sets:
- Greninja V-UNION Special Card Set (Japanese: スペシャルカードセット ゲッコウガV-UNION)
- Mewtwo V-UNION Special Card Set (Japanese: スペシャルカードセット ミュウツーV-UNION)
- Zacian V-UNION Special Card Set (Japanese: スペシャルカードセット ザシアンV-UNION)
Individual Pokémon V-UNION parts have different numbers and the assembly form a numbered master set. Each set also includes a Supporter card depicting Professor Burnet that can aid players in discarding Pokémon V-UNION cards and bring them into play, plus three Skyscraping Perfection booster packs and three Blue Sky Stream booster packs.
In Thailand and Indonesia, cards included in this set were not released as products, and were instead packed into promotional card packs with each pack containing all parts of one of the Pokémon V-UNION and one Professor Burnet card. In addition, the cards are listed as S-P Promotional cards instead of an individual set.