Azure and Crimson both became contestants on the television program Sinnoh Pokémon Hustle, which was fabricated by Team Rocket with the hopes of stealing Pokémon. Officer Jenny had been tracking the two for quite some time and disguised herself in order to follow them.
Azure showed off his acrobatic skills as he and Crimson were some of the few people able to beat the challenges in the game show. He and Crimson eventually came across the box that Team Rocket had been keeping all of the Poké Balls that they took from the other contestants, and decided to help themselves to it. Team Rocket mistook Azure and Crimson as members of their organization who were sent by Giovanni, and helped them escape from Officer Jenny.
Azure and Crimson eventually revealed that they were not members of Team Rocket. A battle then ensued between the two criminal teams. Azure used his Drowzee in a Tag Battle with Crimson and her Zangoose. Both easily defeated Meowth and Jessie's Yanmega, but eventually fell to Officer Jenny's Growlithe. Both Azure and Crimson were then arrested by Officer Jenny and taken to jail.
Azure's only known Pokémon is a Drowzee, which proved to be quite powerful. It was able to easily send Team Rocket blasting off, and was able to hold its own against Officer Jenny and her Growlithe but was eventually defeated.