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In Talking a Good Game!, Anabel first called on Alakazam to help her and Ash when they were attacked by Team Rocket. Alakazam was able to beat them with its powerful Psychic attack. Ash then realized that Anabel was a Frontier Brain and that he would have to battle Alakazam. Ash chose Corphish for the match. Anabel had the ability to telepathically communicate with her Pokémon and give them commands without saying a word. In the end, Alakazam easily defeated Corphish. Alakazam then went on to defeat Ash's Tauros before finally being defeated by his Pikachu, but not before weakening it.
In Second Time's the Charm!, Ash had a rematch with Anabel. Again, she chose Alakazam as her first Pokémon. It went head to head against Ash's Corphish once again, but this time with a little bit of luck as well as Ash's quick thinking, Alakazam was defeated by Corphish's Bubble Beam.