| Protagonists
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Liko (Meowscarada • Pagogo) • Roy (Skeledirge)
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| Rising Volt Tacklers
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Friede (Captain Pikachu) • Mollie • Orla • Ludlow • Murdock • Dot (Quaxwell) • Ult
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| Explorers
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Onia • Zirc • Hamber • Spinel • Coral • Sidian • Chalce • Gibeon • Indi • Rubina
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| Relatives
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Lucius (Rayquaza • Six Heroes) • Rystal • Layla • Diana • Alex • Lucca • Roy's grandfather • Roy's parents • Franka • Cervantis • Maria • Mollie's mother • Ult's father
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| Supporting cast
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Nurse Joy • Steven Stone • Rotom Phones • Ann • Liko's homeroom teacher • Amethio (Zygarde) • Nemona • Iono • Karna • Clavell • Geeta • Dendra • Jacq • Penny • Niko • Rob • Dash • Raifort • Perrin • Carmine • Briar • Master Mayonnaise • Emma • Cyrano • Gym Leaders • Elite Four • Many temporary characters
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