| Protagonists
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Liko (Sprigatito) • Roy (Fuecoco)
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| Rising Volt Tacklers
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Friede (Captain Pikachu) • Mollie • Orla • Ludlow • Murdock • Dot (Quaxly)
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| Explorers
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Amethio • Onia • Zirc • Hamber • Spinel • Sango • Onyx • Agate • Gibeon
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| Relatives
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Alex • Lucca • Diana • Roy's grandfather
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| Supporting cast
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Nurse Joy • Rotom Phones • Ann • Terapagos • Lucius • Nemona • Mitchell • Gym Leaders • Many temporary characters
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