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Alain's Charizard

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===In the ''[[Mega Evolution Specials]]''===
[[File:Alain Charmander.png|thumb|left|250px|As a Charmander]]
Alain met Charizard as a {{p|Charmander}} when he was still one of [[Professor Sycamore]]'s assistants. He took Charmander with him on his journey to find [[Mega Stone]]s.
After Alain left [[Lysandre Labs]] to help Mairin's [[Chespie]] wake up from its coma, Charizard battled a Trainer's Mega {{p|Banette}}.
===In the main seriesKalos===
Charizard's first main series appearance occurred in ''[[XY106|A Meeting of Two Journeys!]]'', where it was first used to save [[Ash's Pikachu]] from {{TRT}} and saving him from a nasty fall as well. It was then used in a battle against {{Ash}} and his {{AP|Greninja}}. Charizard was able to hold the upper hand despite a type-disadvantage, destroying Greninja's {{m|Water Shuriken}} with Dragon Claw, and dodging Greninja's attempts to hit it with {{m|Cut}}. It retaliated with Flamethrower, hitting Greninja. Afterwards, Charizard Mega Evolved and attacked with Dragon Claw, although Greninja countered with Cut. Greninja attempted to confuse Charizard with {{m|Double Team}}, but it countered by destroying all the copies with Flamethrower. Greninja then attempted to hit Charizard with a surprise {{m|Aerial Ace}}, but Charizard revealed its newly learned {{m|Thunder Punch}} to knock Greninja away. Greninja tried to retaliate with Water Shuriken, but Charizard proved to be faster and hit it with a second Thunder Punch. When the battle seemed to be over, Greninja transformed into its Ash-Greninja Form and managed get a good hit on Charizard. It, however, quickly recovered and used Thunder Punch, which Greninja blocked with Cut. Charizard was then able to break through Cut and finished Greninja off with Blast Burn.