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* {{an|Mallow}} received a Grassium Z from Tapu Koko in ''[[SM121|A Recipe for Success!]]'' after she cleared a trial set up by {{an|Oranguru}}. | * {{an|Mallow}} received a Grassium Z from Tapu Koko in ''[[SM121|A Recipe for Success!]]'' after she cleared a trial set up by {{an|Oranguru}}. | ||
* A young Professor Kukui was revealed to own a Firium Z in ''[[SM125|A Timeless Encounter!]]''. In the same episode, Ash also received a Firium Z from a Totem {{p|Trevenant}}. | * A young Professor Kukui was revealed to own a Firium Z in ''[[SM125|A Timeless Encounter!]]''. In the same episode, Ash also received a Firium Z from a Totem {{p|Trevenant}}. | ||
* Hau used a [[Decidium Z]] with his {{p|Decidueye}} in his battle against Ash in ''[[SM132]]''. | |||
* Gladion used his Ghostium Z with his {{p|Zoroark}} in his battle against in Ash in ''[[SM139]]''. | |||
A full set of replicas of the type-specific Z-Crystals appeared in ''[[SM025|A Team-on-Team Tussle!]]''. These replicas were shown to Ash and {{ashcl}} by Professor Kukui. | A full set of replicas of the type-specific Z-Crystals appeared in ''[[SM025|A Team-on-Team Tussle!]]''. These replicas were shown to Ash and {{ashcl}} by Professor Kukui. |
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