Super Smash Bros.

Super Smash Brothers is a video game for the Nintendo 64. It was a game in which characters from various Nintendo video games fought each other. It featured Poké Balls as items and Pikachu and Jigglypuff as playable characters; Pikachu was playable from the start and Jigglypuff had to be unlocked.

In its sequel, Super Smash Brothers Melee, Pichu and Mewtwo were also playable.

Throwing a Pokéball also produces one of a number of Pokémon, that can affect the battle in some way.