From Bulbapedia, the community-driven Pokémon encyclopedia.
Number. Pokémon - How I got it - Self-created Pokéball used
1. Empoleon♂ - Starter as Piplup - Aqua ball
2. Absol♂ - 1st caught - Darkness ball
3. Staraptor♂ - 2nd caught as Starly - Air ball
4. Electivire♂ - 3rd caught as Elekid - Thunder ball
5. Gallade♂ - 4th caught as Ralts - Psych ball
6. Magmortar♂ - 5th caught as Magby - Flame ball
I don't have one at the moment.
One of the Gen IV ones, but I dunno which one.
Projects I'm helping in
And nothing else so far.