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In the games, there will, on rare occasions, come up a Pokémon that knows a move it cannot legally learn in any game. It is unknown whether these are actual mistakes or not.
List of in-game Pokémon with moves they can't learn in the games
This is the eighth trainer in Poké Cup Ultra Ball R-2. While Blastoise can learn these moves by breeding, it cannot learn both simultaneously, as there is no Pokémon in the same egg group as Blastoise that can learn both of these moves.
Lt. Surge has this Raichu when fighting him in R-2. While Raichu can learn both of these moves individually, there is no way for it to legally know both moves simultaneously. Surf can only be obtained as a special move as a Pikachu in Pokémon Stadium, while Reversal can only be obtained by breeding.
The Bonsly usable in the Battle Bingo knows Rock Slide, though Bonsly could not legitimately learn any moves in Pokémon XD: Gale of Darkness, and as such, could not legitimately learn Rock Slide until Generation IV. This was likely done so that players could use Bonsly in battle.