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In Shield with a Twist!, Ash used it in his Gymbattle with Fantina. Amazed with the method, Fantina named it the Counter Shield. It eventually helped Ash with his battle, earning him the Relic Badge.
In When Regions Collide!, Brock commanded his Geodude and Steelix to use Gyro Ball to deflect attacks, and mentioned that "a certain challenger of his" taught him to use a Pokémon's attack as a means of defense.
Chimchar/Monferno uses Flamethrower while using Flame Wheel to create flame whips that prevent foes from getting closer while also hitting the opponent.
Buizel spins on his back while using Aqua Jet to create a water tornado or Water Gun to create water whips in order to protect himself from the opponent's attacks.
Drifblim uses Will-O-Wisp to surround its body in fire wisps. Then it uses Psychic to move the fire in two circles. Drifblim can either shoot the flames as an attack or keep the fire around it as a defense tactic.
Gastrodon uses Muddy Water to make a tornado made of water around it to avoid its opponent getting closer to it because it is slower. However, it will purposely leave an opening at the bottom of its body to entice opponents to strike there, so Gastrodon can counterattack in retaliation.
Inteleon uses Aqua Jet while spinning to protect itself in a vortex of water and create water whips that sweep the battlefield in a circular motion and strike the opponent.
During her battle against Conway in Camping It Up!, Dawn commanded the Grimer she borrowed from the Pokémon Summer Academy to use Poison Gas while spinning to surround its body with smoke in order to avoid the opponent's attacks. This was shown to work the same way as the Counter Shield but was used before the tactic was introduced to the series.